Bis(μ-2-methylquinolin-8-olato)-κ3N,O:O;κ3O:N,O-bis[(methanol-κO)(nitrato-κ2O,O′)lead(II)]
Bis(μ-2-methylquinolin-8-olato)-κ3N,O:O;κ3O:N,O-bis[(methanol-κO)(nitrato-κ2O,O′)lead(II)]
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The molecule of the title compound, [Pb2(C10H8NO)2(NO3)2(CH3OH)2], Lipo 6 lies about a centre of inversion.The Pb atom is chelated by nitrate and substituted quinolin-8-olate anions.The O atom of the quinolin-8-olate also bridges, to confer a six-coordinate status on the Crochet Notions metal centre.
When a longer Pb.O interaction is considered, the geometry approximates a Ψ-cube in which one of the sites is occupied by a stereochemically active lone pair.